Preheat oven to 350℉. Spray the muffin tray with olive oil.
In a mini food processor, pulse the broccoli florets for a few seconds until finely chopped. Transfer broccoli a large bowl. Add in the eggs, cottage cheese, olive oil, garlic and whisk together until combined. Next, add in the potato starch, almond flour, baking powder, salt and mix until incorporated. Fold in the cheddar cheese. Then, divide equally amongst 10 slots. Sprinkle muffins with cheese and toasted sesame seeds. Bake for 25-27 minutes or until golden on the edges.